Carlos Alcaraz kicks things off against Alexandre Muller before Iga Swiatek takes on no30 seed Petra Martic. Djokovic faces two-time quarter-finalist Stan Wawrinka.
Given the stacked schedule, British no1 Cameron Norrie is demoted to Court One after a two-day break. He takes on Christopher Eubanks after no2 seed Aryna Sabalenka looks to see off Varvara Gracheva. Ons Jabeur, a finalist last year, rounds off the day against Zhuoxuan Bai.
Elsewhere, there is a quick turnaround for British hope Liam Broady, whose reward for beating Casper Ruud is a clash with Denis Shapovalov.
Here’s how Friday looks in SW19…
Wimbledon day five schedule | Order of play for Friday, July 6, 2023
All times BST, from 11am unless stated. Seeds in brackets.
Centre Court (from 1.30pm)
Carlos Alcaraz (1) vs Alexandre Muller
Iga Swiatek (1) vs Petra Martic (30)
Stan Wawrinka vs Novak Djokovic (2)
Wimbledon 2023 | Best Pictures
Court One (from 1pm)
Varvara Gracheva vs Aryna Sabalenka (2)
Cameron Norrie (12) vs Christopher Eubanks
Ons Jabeur (6) vs Zhuoxuan Bai
Court Two
Aliaksandra Sasnovich vs Petra Kvitova (9)
Alexander Zverev (19) vs Yosuke Watanuki
Denis Shapovalov (26) vs Liam Broady
Marie Bouzkova (32) vs Caroline Garcia (5)
Court 3
Roberto Carballes Baena vs Holger Vitus Nodskov Rune (6)
Jannik Sinner (8) vs Quentin Halys
Jessica Pegula (4) vs Elisabetta Cocciaretto
Elina Svitolina vs Sofia Kenin
Court 12
Viktorija Golubic vs Madison Keys (25)
Lorenzo Musetti (14) vs Hubert Hurkacz (17)
Daria Kasatkina (11) vs (19) Victoria Azarenka (19)
Andrey Rublev (7) vs David Goffin
Court 18
Marta Kostyuk vs Paula Badosa Gibert
Matteo Berrettini vs Alex De Minaur (15)
Alexander Bublik vs Maximilian Marterer
Court 8
Natalija Stevanovic vs Tamara Korpatsch
Jason Kubler vs Nicolas Jarry (25)
Court 11
Jule Niemeier vs Dalma Galfi
Guido Pella vs Roman Safiullin
Court 14
Christopher O’Connell vs Jiri Vesely
Lesia Tsurenko vs Ana Bogdan
Magda Linette (23) vs Belinda Bencic (14)
Court 15
Irina-Camelia Begu (29) vs Anna Blinkova
Alejandro Davidovich Fokina (31) vs Botic Van de Zandschulp
